Relative abundance (%) Retention time (min) Figure S1. Total ion chromatogram of SP 1.

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1 Relative abundance (%) Retention time (min) Figure S1. Total ion chromatogram of SP

2 Relative abundance (%) Retention time (min) Figure S. Total ion chromatogram of SP

3 Relative abundance (%) Retention time (min) Figure S3. Total ion chromatogram of esterified SP 3.

4 Relative abundance (%) Retention time (min) Figure S4. Total ion chromatogram of esterified SP 4.

5 Relative abundance (%) Retention time (min) Figure S5. Total ion chromatogram of esterified SP 5.

6 Relative abundance (%) Retention time (min) Figure S. Total ion chromatogram of esterified IEP.

7 Table S1. HCs Detected in SP 1, SP and Esterified SP 3 and SP 4 According to Analysis with GC/MS. peak HC SP 1 SP SP 3 SP 4 3 benzene toluene. 33 3,4-dimethylpent--ene ethylidene-1-methylcyclopent-1-ene ethylbenzene m-xylene styrene 7 p-xylene isopropylcyclohexane ,,5,5-tetramethylcyclopenta-1,3-diene ,,3,4,5-pentamethylcyclopenta-1,3-diene.35 1 pentylcyclopentane ethyloctane ,-dimethylcyclohexane ethyl-,4-xylene.1 19 naphthalene ,5-dimethyl-tetralin.53 5 sec-butylcyclohexane ,,3-trimethyl-1H-indene (but--enyl)-1,-xylene ,,-trimethyl-1H-indene.5 31 tetradecane ,4,-timethyl-1,-dihydronaphthalene.1 31,5,-trimethyl-1,-dihydronaphthalene ,4,5-trimethyl-1,-dihydronaphthalene ethyltridecane pentadecane isopropyl-,3,4,5-tetramethylbenzene. 3 1,4-diisopropyl-,5-xylene.4 375,1-dimethyl--methyleneundecane ethyl-3,5-diisopropylbenzene tetracene tetraphene.3 4 chrysene triphenylene.1

8 Table S. Alcohols Detected in SP 1, SP and Esterified SP 5 and IEP According to Analysis with GC/MS. peak alcohol SP 1 SP SP 5 IEP ethane-1,-diol propane-1,-diol.9 17 butane-1,-diol furan-3-ylmethanol.95 5 butane-,3-diol. cyclopentanol.4 3 butane-,3-diol butane-1,3-diol.13 3,3-dimethylbutan-1-ol. 41 -methylpentan-1-ol methoxybutan-1-ol. 47 butane-1,1-diol methylcyclopentanol.4 5 -methylpent--en-1-ol. 5 1-methoxybutan--ol butane-,-diol. -methylhexan-3-ol methylhexan-3-ol methoxybutan-1-ol methylcyclohexanol ,3,4-trimethylpentan-3-ol. 73,4-dimethylcyclopentanol.11 74,3-dimethylcyclopentanol ,4-dimethylcyclopentanol.1 79,-dimethylcyclopentanol.1. 1,4-dimethylpentan-3-ol 1.3 9,-dimethylcyclohexanol.9 94 butane-1,4-diol methylcyclohexanol. 1,3-dimethylcyclohexanol ,4-dimethylcyclohexanol.1 1 pentane-1,4-diol.5 111,4-dimethylcyclohexanol ,-dimethylheptan-4-ol.1 11,5-dimethylcyclohexanol. 117 cyclopentane-1,-diol ,3-dimethylcyclohexanol ethylpentan-1-ol. 1,4,4-trimethylcyclopentanol ,5-dimethylcyclohexanol methylcyclopentane-1,-diol methylcyclopentane-1,-diol 1.

9 Table S. Alcohols Detected in SP 1, SP and Esterified SP 5 and IEP According to Analysis with GC/MS (Continued). peak alcohol SP 1 SP SP 5 IEP 14,3-dimethylpentan-1-ol cyclohex--enol.9 147,-dimethylpentan-1-ol methylcyclopentane-1,3-diol methyloct-5-en--ol methylcyclohexane-1,-diol methylcyclohexane-1,-diol methylhexan-1-ol.7 17 cyclohexane-1,4-diol. 3 -methyl--propylpropane-1,3-diol cyclohexenylethanol.1 49 (4-(tert-butyl)phenyl)methanol.9 55 nona-3,5-dien--ol.7 37,1,14-trimethylpentadecan--ol.7

10 Table S3. Ethers Detected in SP 1, SP and Esterified SP 3, SP 5 and IEP According to Analysis with GC/MS. peak ether SP 1 SP SP 3 SP 5 IEP 1,-dimethoxypropane ethoxy-1-methoxyethane ,1-diethoxyethane.15 1,-diethoxypropane.7 -methoxy--methylpropane.1 4 -ethoxy--methylbutane.7 5 -isopropyl-1,3-dioxolane methoxypentane methoxycyclohexane. 1 (tetrahydrofuran--yl)methanol methylanisol ethylanisole. 1 1-(allyloxy)octane ,3-dimethylanisole.4 7,4,-trimethylanisole. 17 -methyl-4-methoxyanisol isopropylanisole ,,-trimethoxyhexane ,,4-trimethoxyheptane ,,5-trimethoxyheptane propylbenzo[d][1,3]dioxole.3 9 1,,-trimethoxyheptane isopropyl-4-methylanisole (sec-butyl)anisole propionylanisole (-methoxy-5-methylphenyl)propanal (tert-butyl)anisole isopropyl-4-methylanisol (3-methoxy-5-methylphenyl)propanal butylanisole.4 3,,4,-tetramethyl-,3-dihydrobenzofuran.4 39,,5,-tetramethyl-,3-dihydrobenzofuran.3 373,3,3,4,7-pentamethyl-,3-dihydrobenzofuran.3

11 Table S4. Ketones Detected in SP 1, SP and Esterified SP 3 SP 5 and IEP According to Analysis with GC/MS. Peak ketone SP 1 SP SP 3 SP 4 SP 5 IEP 7 pentan--one.11 1 pentan-3-one. 9 hexan-3-one methylpent-3-en--one isopropoxypropan--one hydroxy-4-methylpentan--one ,3-dimethylcyclopent--enone. 99 -methylheptan-4-one. 14 3,3,5-trimethylcyclohexanone methoxy--methylhexan-3-one ethylnonan-4-one methylcyclohex--enone ,4,4-trimethylcyclopent--enone ,4,5-trimethylcyclopent--enone ,3,4,5-tetramethylcyclopent--enone ,4-dimethylcyclohex--enone.14 nonan-3-one hydroxy-,4,5-trimethylcyclohexa-,5-dienone (benzo[d][1,3]dioxol-5-yl)ethanone (4-(methoxymethyl)-,-dimethylphenyl)ethan-.3 1-one 34 1-(benzo[d][1,3]dioxol-5-yl)propan--one (benzo[d][1,3]dioxol-5-yl)propan-1-one methoxy-4-methyl-H-chromen--one (3-methoxyphenyl)but-3-en--one (7-methoxybenzofuran--yl)ethanone. 39 5,-dimethoxy-H-chromen--one ,-di-tert-butylcyclohexa-,5-diene-1,4-dione.1

12 Table S5. CAs Detected in SP 1 and SP According to Analysis with GC/MS. Peak CA SP 1 SP 4 propionic acid isobutyric acid.9.9 butyric acid methylbutanoic acid.5 4 -methylbutanoic acid. 91 -methylpentanoic acid methylpentanoic acid methylpent--enoic acid methylhexanoic acid methylhexanoic acid methylheptanoic acid.4 9 octanoic acid.4 5 nonanoic acid (,5-dimethoxyphenyl)acrylic acid.4

13 Table S. Other esters Detected in SP and Esterified SP 3, SP 5 and IEP According to Analysis with GC/MS. Peak other ester SP SP 3 SP 5 IEP 11 ethyl methyl carbonate methyldihydrofuran-(3H)-one ethyl methyl succinate ethyl methyl glutarate cyclohexyl acetate.4 3 methyl -(7,7-dimethyl-1-oxo-,3,4,5,,7-.39 hexahydro-1h-inden--yl)acetate 31 methyl -(5,7,7-trimethyl-1-oxo-,3,4,5,,7-.75 hexahydro-1h-inden--yl)acetate 3 methyl -(5,,7-trimethyl-1-oxo-,3,4,5,,7- hexahydro-1h-inden--yl)acetate.54

14 Table S7. NCOCs Detected in SP 1, SP and Esterified SP 5 and IEP According to Analysis with GC/MS. peak NCOC SP 1 SP SP 5 IEP propan--one oxime. 19 acetamide. 1-methylpiperidine.1 37 N-methylacetamide ,3-dimethylpiperidine.5 51 propionamide.59 7 isobutyramide.17 N-methylpropionamide N,N-dimethylheptan-1-amine.17 7 N-methylpropan--amine.4,4-dimethylpyridine.3 11,4,-trimethylpyridine ,1,,-tetramethylhydrazine methylpyrrolidin--one methylpyrrolidine-,5-dione ethyl--methylpiperidine.5,,4,5,5-pentamethyl-,5-dihydro-1H-imidazol-1-ol. 4 -(but--enylidene)-1,1-dimethylhydrazine ,5-dimethyl-1H-pyrazole-1-carboximidamide butylthiazole.57 53,3-diethylpyrazine.1 9,4,-trimethylbenzene-1,3-diamine methyl-1H-indole methoxy-1H-benzo[d]imidazol-(3h)-one (tert-butyl)-1h-benzo[d]imidazole. 345,3,5-trimethyl--(prop-1-enyl)pyrazine (4-aminophenyl)ethanone ((isopropylimino)methyl)-N,N-dimethylaniline ,4,5,7-tetramethylfuro[3,4-d]pyridazine methyl-4-phenylthiazol--amine.4 39 methyl 4-(ethylamino)benzoate ,-dimethylquinolin-(1H)-one.34

15 Table S. Others Detected in SP 1, SP and Esterified SP 3 SP 5 and IEP According to Analysis with GC/MS. peak other SP 1 SP SP 3 SP 4 SP 5 IEP 5 1-methyl--propyldisulfane ethyltrimethylsilane (trimethylsilyl)methanol.1 7 -methylthietane.5 methylsulfonylmethane.31 1 S,S-dimethyl carbonodithioate ,3-dimethyltrisulfane isobutyric anhydride methylpentanal (tetrahydro-h-pyran--yl)methanol methylhept--enal (-methylcyclohex-1-enyl)but--enal.7 33,3-diethylbenzo[b]thiophene. 371,7-diethylbenzo[b]thiophene (3,5-dimethylbenzo[b]thiophen--yl)ethanone (,5-dimethylbenzo[b]thiophen-3-yl)ethanone.37